Product ID:ETHYL ACETATE E3260, ET105
MSDS Date:12/17/1996
FSC:6810
NIIN:00N089859
Status Code:A
MSDS Number: CHWPQ

SPECTRUM CHEMICAL MFG CORP

14422 SOUTH SAN PEDRO ST
GARDENA, CA 90248
US

Emergency Phone: 800-414-9300(CHEMTREC)

Info Phone: 310-516-8000

Preparer: E. BRULL

Cage: 63415

SPECTRUM LABORATORY PRODUCTS INC

GARDENA, CA 90248-2027 US

Telephone: 310-516-9843

Cage: 63415

ACETIC ACID, ETHYL ESTER; (ETHYL ACETATE) (CERCLA). LD50

CAS: 141-78-6

RTECS: AH5425000

Fraction By Weight: 100%

OSHA PEL 400 PPM

ACGIH TLV: 400 PPM

EPA Report Quantity: 5000 LBS

DOT Report Quantity: 5000 LBS

CREVICES, CREASES & GROIN. COLD WATER MAY BE USED.

RTECS: 9999999ZZ

SEEK MED ATTN. WASH CONTAM CLTHG BEFORE REUSING.

RTECS: 9999999ZZ

CONTAM SKIN W/ANTI-BACTERIAL CREAM. SEEK IMMED MED

RTECS: 9999999ZZ

EVACUATE TO SAFE AREA AS SOON AS

RTECS: 9999999ZZ

IF NOT BRTHG, PERFORM MOUTH-TO-MOUTH RESUSCITATION.

RTECS: 9999999ZZ

GIVE MOUTH-TO-MOUTH RESUSCITATION WHEN INHALED MATL

RTECS: 9999999ZZ

REMOVE DENTURES IF ANY. WATCH FOR OBSTRUCTION IN

RTECS: 9999999ZZ

BETWEEN TEETH. HAVE CONSCIOUS PERSON DRINK SEVERAL

RTECS: 9999999ZZ

IN THROAT. SEEK IMMED MED ATTN. SERIOUS

RTECS: 9999999ZZ

INDICATION THAT TOX MATL INGESTED; ABSENCE OF SUCH

RTECS: 9999999ZZ

ANY. WATCH FOR OBSTRUCTION IN MOUTH; REMOVE IF POSS

RTECS: 9999999ZZ

TEETH. IF SOFT PAD CAN BE INSERTED BETWEEN TEETH,

RTECS: 9999999ZZ

TONGUE IMMENSELY COMPLICATES PATIENT'S PROBS. HAVE

RTECS: 9999999ZZ

INDUCE VOMIT BY STICKING FINGER IN THROAT. LOWER

RTECS: 9999999ZZ

OCCUR, DO NOT RESTRAIN VICTIM, BUT REMOVE OBJECTS

RTECS: 9999999ZZ

PVNT FROM STRIKING FIXED HEAVY OBJECTS. IF CONVLS

RTECS: 9999999ZZ

MOUTH WILL DRAIN. SEEK IMMED MED ATTN.

RTECS: 9999999ZZ

TOUCH SPILLED MATL. PVNT ENRY INTO SEWERS,

RTECS: 9999999ZZ

SOURCES OF IGNIT. PERSONAL PROT IN CASE OF LG

RTECS: 9999999ZZ

VAP RESP. BOOTS. GLOVES. NIOSH APPRVD SCBA TO AVOID

RTECS: 9999999ZZ

SUFFICIENT; CONSULT SPECIALIST BEFORE HANDLING THIS

RTECS: 9999999ZZ

VENTD PLACE. GROUND EQUIP CNTNG MATL.

RTECS: 9999999ZZ

MED ADVICE IMMED & SHOW CONTAINER OR LABEL.

RTECS: 9999999ZZ

LD50 LC50 Mixture:SEE INGREDIENT 1
Routes of Entry: Inhalation:YES Skin:YES Ingestion:YES
Reports of Carcinogenicity:NTP:NO IARC:NO OSHA:NO
Health Hazards Acute and Chronic:ACUTE: VERY DANGEROUS IN CASE OF
INGESTION. SLIGHTLY DANGEROUS TO DANGEROUS IN CASE OF SKIN CONTACT
(IRRITANT), OF EYE CONTACT (IRRITANT), OF INHALATION. VERY SLIGHTLY
TO SLIGHTLY DANGEROUS IN CASE OF SKIN CONTACT (PERMEATOR). SEVERE
OVEREXP CAN RESULT IN DEATH. CAN BE FATAL IF INHALED OR INGESTED.
(EFTS OF OVEREXP)
Explanation of Carcinogenicity:NOT RELEVANT
Effects of Overexposure:HLTH HAZ: THIS PRODUCT MAY IRRITATE EYES & SKIN
UPON CONTACT. CHRONIC: THIS SUBSTANCE IS TOXIC TO LUNGS, MUC MEMBS.
TOXICITY OF PROD TO REPRO SYS: NOT AVAIL. RPTD/PRLNGD EXPOS TO
SUBSTANCE CAN PRDCE T ARGET ORGANS DAMAGE. RPTD EXPOS TO HIGHLY TOX
MATL MAY PRDCE GEN DETERIORATION OF HLTH BY ACCUM IN ONE/MANY
ORGANS.
Medical Cond Aggravated by Exposure:NONE SPECIFIED BY MANUFACTURER.

First Aid:EYES: CHECK FOR & REMOVE CNTCT LENSES. IMMED FLUSH W/RUNNING
WATER FOR AT LST 15 MIN, KEEPING LIDS OPEN. COLD WATER MAY BE USED.
DO NOT USE EYE OINTMENT. SEEK MED ATTN. SKIN: IF CHEM GOT ONTO
CLOTHED PORTION OF BODY, REMOVE CONTAMD CLOTHESAS QUICKLY AS POSS,
PROTECTING YOUR OWN HANDS & BODY. PLACE VICTIM UNDER DELUGE SHOWER.
IF CHEM TOUCHES VICTIM'S EXPOS SKIN, SUCH AS HANDS: GENTLY &
(SUPDAT)

Flash Point Method:TCC
Flash Point:24.1F,-4.4C
Lower Limits:2.2%
Upper Limits:11.5%
Extinguishing Media:SMALL FIRE: USE DRY CHEMS, CO*2, ALCOHOL FOAM OR
WATER SPRAY. LARGE FIRE: USE ALCOHOL FOAM, WATER SPRAY OR FOG.
Fire Fighting Procedures:USE NIOSH APPRVD SCBA & FULL PROT EQUIP . FLAM
LIQ, SOL/DISPERSED IN WATER. COOL CONTAINING VESSELS W/WATER JET IN
ORDER TO PVNT PRESS BUILD-UP, (SUPDAT)
Unusual Fire/Explosion Hazard:PRODS OF COMBUST ARE CARBON OXIDES (CO,
CO*2). SLIGHTLY FLAM IN PRESENCE OF OPEN FLAMES & SPKS. VERY
SLIGHTLY TO SLIGHTLY FLAM & EXPLO IN PRESENCE OF (SUPDAT)

Spill Release Procedures:LG SPILL:DILUTE W/WATER & MOP UP OR ABSORB
W/INERT DRY MATL & PLACE IN APPRVD WASTE DISP CNTNR. LG SPILL: FLAM
LIQ. KEEP AWAY FROM HEAT & SOURCES OF IGNIT. STOP LEAK IF W/OUT
RISK. ABSORB W/DRY EARTH, SAND/OTHER NON-COMBUST MATL. DO NOT (ING
19)
Neutralizing Agent:NONE SPECIFIED BY MANUFACTURER.

Handling and Storage Precautions:STORE FLAM MATLS IN SEPARATE SFTY STOR
CABINET/ROOM. KEEP AWAY FROM HEAT & SOURCES OF IGNIT. KEEP CNTNR
TIGHTLY CLSD. KEEP IN COOL, WELL (ING 23)
Other Precautions:KEEP LOCKED UP. KEEP AWAY FROM HEAT & SOURCES OF
IGNIT. GROUND ALL EQUIP CONTAINING MATL. DO NOT INGEST. DO NOT
BREATHE GAS, FUMES, VAP/SPRAY. IN CASE OF INSUFFICIENT VENT, WEAR
SUITABLE NIOSH APPRVD RESP EQUIP. IF INGESTED, SEEK (ING 24)

Respiratory Protection:VAPOR RESPIRATOR. BE SURE TO USE NIOSH APPROVED
RESPIRATOR. WEAR APPROPRIATE RESPIRATOR WHEN VENTILATION IS
INADEQUATE.
Ventilation:PROVIDE EXHST VENT OR OTHER ENGINEERING CTLS TO KEEP
AIRBORNE CONCS OF VAPS BELOW THEIR RESPECTIVE THRESHOLD LIM VALUE.
Protective Gloves:IMPERVIOUS GLOVES.
Eye Protection:ANSI APPRVD CHEM WORKERS GOGGLES .
Other Protective Equipment:ANSI APPROVED EYE WASH & DELUGE SHOWER ;
ENSURE PROXIMAL TO WORK-STATION LOCATION. LAB COAT.
Work Hygienic Practices:NONE SPECIFIED BY MANUFACTURER.
Supplemental Safety and Health
SOL IN H*2O: PARTIALLY SOL IN COLD WATER. FL PT/METH: 45F,7.2C/COC.
FIRE FIGHT PROC: AUTOIGNIT/EXPLO. EXPLO HAZ: OXIDIZING MATLS, OF
ACIDS, OF ALKALIS. MATL TO AVOID: IN PRESENCE OF GLASS. FIRST AID P
ROC: THOROUGHLY WASH CONTAM SKIN W/RUNNING WATER & NON-ABRASIVE
SOAP. BE PARTICULARLY CAREFUL TO CLEAN FOLDS, (ING 2)

Boiling Pt:B.P. Text:171F,77C
Melt/Freeze Pt:M.P/F.P Text:-117F,-83C
Vapor Pres:73 @ 20C
Vapor Density:3.04
Spec Gravity:0.902 (H*2O=1)
Solubility in Water:SUPDAT
Appearance and Odor:LIQUID.

Stability Indicator/Materials to Avoid:YES
NO SPECIFIC INFO AVAIL IN DATABASE REGARDING REACTIVITY OF MATL IN
PRESENCE OF VARIOUS OTHER MATLS. NON-CORR (SUPDAT)
Stability Condition to Avoid:NO ADDITIONAL REMARK.
Hazardous Decomposition Products:NONE SPECIFIED BY MANUFACTURER.

Waste Disposal Methods:RECYCLE TO PROCESS, IF POSSIBLE. CONSULT YOUR
FEDERAL, STATE, LOCAL OR REGIONAL AUTHORITIES.

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This information is formulated for use by elements of the Department
of Defense. The United States of America in no manner whatsoever,
expressly or implied, warrants this information to be accurate and
disclaims all liability for its use. Any person utilizing this
document should seek competent professional advice to verify and
assume responsibility for the suitability of this information to their
particular situation.